Stannous Chloride Dihydrate (Solid):
H317 May cause an allergic skin reaction.
H335 May cause respiratory irritation.
H314 Causes severe skin burns and eye damage.
H318 Causes serious eye damage.
H341 Suspected of causing genetic defects.
H361 Suspected of damaging fertility or the unborn child.
�� Classification of the substance or mixture
Germ Cell Mutagenicity 2
Toxic to Reproduction 2
2 Hazard(s) identification
1 Identification
Specific Target Organ Toxicity ��� Repeated Exposure 2 H373 May cause damage to organs through prolonged or
repeated exposure.
Skin Corrosion 1A
Eye Damage 1
Sensitization ��� Skin 1
Specific Target Organ Toxicity ��� Single Exposure 3
*
��
Acute Toxicity ��� Inhalation 4 H332 Harmful if inhaled.
Label elements
�� GHS label elements The substance is classified and labeled according to the Globally Harmonized System (GHS).
REACTIVITY 0
FIRE 0
HEALTH 2
�� Hazard pictograms
�� Signal word Danger
�� Hazard statements
Harmful if inhaled.
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
Suspected of causing genetic defects.
Suspected of damaging fertility or the unborn child.
May cause respiratory irritation.
May cause damage to organs through prolonged or repeated exposure.
�� Precautionary statements
Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood.
Do not breathe dusts or mists.
Wash thoroughly after handling.
Use only outdoors or in a well-ventilated area.
Contaminated work clothing must not be allowed out of the workplace.
Wear protective gloves/protective clothing/eye protection/face protection.
If swallowed: Rinse mouth. Do NOT induce vomiting.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a poison center/doctor.
IF exposed or concerned: Get medical advice/attention.
Specific treatment (see on this label).
Get medical advice/attention if you feel unwell.
If skin irritation or rash occurs: Get medical advice/attention.
Wash contaminated clothing before reuse.
Store in a well-ventilated place. Keep container tightly closed.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
�� Classification system:
�� NFPA ratings (scale 0 ��� 4)
Health = 2
Fire = 0
Reactivity = 0
�� HMIS-ratings (scale 0 ��� 4)
Health = 2
Fire = 0
Reactivity = 0
�� Other hazards
�� Results of PBT and vPvB assessment
�� PBT: Not applicable.
Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Environmental precautions: Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Use neutralizing agent.
Dispose contaminated material as waste according to section 13.
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
Protective Action Criteria for Chemicals
PAC-1: 11 mg/m��
PAC-2: 20 mg/m��
6 Stannous Chloride Dihydrate (Solid) ��� Accidental release measures
�� vPvB: Not applicable.
Chemical characterization: Substances
CAS: 10025-69-1 Stannous Chloride Dihydrate 100%
3 Stannous Chloride Dihydrate (Solid) ��� Composition/information on ingredients
Description of first aid measures
General information:
Immediately remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours
after the accident.
After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact: Immediately wash with water and soap and rinse thoroughly.
After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing: Drink copious amounts of water and provide fresh air. Immediately call a doctor.
Information for doctor:
Most important symptoms and effects, both acute and delayed No further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
4 Stannous Chloride Dihydrate (Solid) ��� First-aid measures
Extinguishing media
Suitable extinguishing agents: Use fire fighting measures that suit the environment.
Special hazards arising from the substance or mixture No further relevant information available.
Advice for firefighters
Protective equipment: Mouth respiratory protective device.
5 Stannous Chloride Dihydrate (Solid) ��� Fire-fighting measures
Additional information about design of technical systems: No further data; see section 7.
Control parameters
Additional information: The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
respiratory protective device that is independent of circulating air.
Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture.
8 Exposure controls/personal protection
�� Components with limit values that require monitoring at the workplace:
CAS: 10025-69-1 Stannous chloride dihydrate
PEL
REL
TLV
Long-term value: 2 mg/m��
as Sn
Long-term value: 2 mg/m��
as Sn
Long-term value: 2* mg/m��
*inhalable fraction, as Sn
(Contd. of page 3)
�� PAC-3: 760 mg/m��
Handling:
Precautions for safe handling
Thorough dedusting.
Ensure good ventilation/exhaustion at the workplace.
Information about protection against explosions and fires: No special measures required.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles: No special requirements.
Information about storage in one common storage facility: Not required.
Further information about storage conditions: Keep receptacle tightly sealed.
Specific end use(s) No further relevant information available.
7 Handling and storage
9 Stannous Chloride Dihydrate (Solid) ��� Physical and chemical properties
�� Information on basic physical and chemical properties
�� General Information
�� Appearance:
Form: Crystals
Color: Colourless
�� Odor: Odorless
�� Odor threshold: Not determined.
�� pH-value: Not applicable.
�� Change in condition
Melting point/Melting range:
Boiling point/Boiling range:
37 ��� 38 ��C
Not applicable.
�� Flash point: Not applicable.
�� Flammability (solid, gaseous): Product is not flammable.
�� Decomposition temperature: Not determined.
�� Ignition temperature: Not determined.
�� Danger of explosion: Product does not present an explosion hazard.
�� Explosion limits:
Lower:
Upper:
Not determined.
Not determined.
�� Vapor pressure: Not applicable.
�� Density at 20 ��C (68 ��F):
�� Relative density
�� Vapor density
�� Evaporation rate
2.71 g/cm��
Not determined.
Not applicable.
Not applicable.
�� Solubility in / Miscibility with
Water:
Not determined.
�� Partition coefficient (n-octanol/water): Not determined.
�� Viscosity:
Dynamic:
Not applicable.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
�� Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer.
�� Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
�� Eye protection:
�� Body protection: Protective work clothing
Information on toxicological effects
Acute toxicity:
Primary irritant effect:
on the skin: Strong caustic effect on skin and mucous membranes.
on the eye:
Strong caustic effect.
Strong irritant with the danger of severe eye injury.
Sensitization: Sensitization possible through skin contact.
Additional toxicological information:
Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus
and stomach.
Carcinogenic categories
IARC (International Agency for Research on Cancer) Substance is not listed.
NTP (National Toxicology Program) Substance is not listed.
OSHA-Ca (Occupational Safety & Health Administration) Substance is not listed.
11 Toxicological information
Toxicity
Aquatic toxicity: No further relevant information available.
Persistence and degradability No further relevant information available.
Behavior in environmental systems:
Bioaccumulative potential No further relevant information available.
Mobility in soil No further relevant information available.
Additional ecological information:
General notes:
Water hazard class 3 (Self-assessment): extremely hazardous for water
Do not allow product to reach ground water, water course or sewage system, even in small quantities.
Must not reach bodies of water or drainage ditch undiluted or unneutralized.
Danger to drinking water if even extremely small quantities leak into the ground.
Results of PBT and vPvB assessment
PBT: Not applicable.
12 Stannous Chloride Dihydrate (Solid) ��� Ecological information
Kinematic: Not applicable.
�� Other information No further relevant information available.
�� LD/LC50 values that are relevant for classification:
Inhalative LC50/4h 1.5 mg/l (ATE)
Reactivity No further relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
Possibility of hazardous reactions No dangerous reactions known.
Conditions to avoid No further relevant information available.
Incompatible materials: No further relevant information available.
Hazardous decomposition products: No dangerous decomposition products known.
10 Stability and reactivity
14 Transport information
*
�� UN-Number
�� DOT, IMDG, IATA
UN3260
�� UN proper shipping name
�� DOT
�� IMDG, IATA
Corrosive solid, acidic, inorganic, n.o.s. (Stannous chloride
dihydrate)
CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. (Stannous
chloride dihydrate)
�� Transport hazard class(es)
�� DOT
�� Class 8 Corrosive substances
�� Label 8
�� IMDG
�� Class 8 Corrosive substances
�� Label 8
�� IATA
�� Class 8 Corrosive substances
�� Label 8
�� Packing group
�� DOT, IMDG, IATA
III
�� Environmental hazards: Environmentally hazardous substance, solid
�� vPvB: Not applicable.
�� Other adverse effects No further relevant information available.
Waste treatment methods
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.
13 Disposal considerations
Safety, health and environmental regulations/legislation specific for the substance or mixture
No further relevant information available.
Sara
Section 355 (extremely hazardous substances): Substance is not listed.
Section 313 (Specific toxic chemical listings): Substance is not listed.
TSCA (Toxic Substances Control Act):
Hazardous Air Pollutants Substance is not listed.
Proposition 65
Chemicals known to cause cancer: Substance is not listed.
Chemicals known to cause reproductive toxicity for females: Substance is not listed.
Chemicals known to cause reproductive toxicity for males: Substance is not listed.
Chemicals known to cause developmental toxicity: Substance is not listed.
Carcinogenic categories
EPA (Environmental Protection Agency) Substance is not listed.
TLV (Threshold Limit Value) Substance is not listed.
NIOSH-Ca (National Institute for Occupational Safety and Health) Substance is not listed.
GHS label elements The substance is classified and labeled according to the Globally Harmonized System (GHS).
Hazard pictograms
Signal word Danger
Hazard statements
Harmful if inhaled.
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
Suspected of causing genetic defects.
Suspected of damaging fertility or the unborn child.
May cause respiratory irritation.
May cause damage to organs through prolonged or repeated exposure.
Precautionary statements
Obtain special instructions before use.
15 Regulatory information
�� Marine pollutant: Symbol (fish and tree)
�� Special precautions for user Warning: Corrosive substances
�� Hazard identification number (Kemler code): 8
�� EMS Number: F-A,S-B
�� Segregation groups (SGG1) Acids
�� Stowage Category A
�� Segregation Code SG36 Stow ���separated from��� SGG18-alkalis.
SG49 Stow ���separated from��� SGG6-cyanides
�� Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code
Not applicable.
�� UN ���Model Regulation���: UN 3260 CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S.
(STANNOUS CHLORIDE DIHYDRATE), 8, III
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
Department issuing SDS: Environment protection department.
Date of preparation / last revision
Creation date for SDS. 28/05/2024.
Revision 1.0, 10/03/2025: Reviewed SDS for accuracy. MH/STN
16 Other information
*
Do not handle until all safety precautions have been read and understood.
Do not breathe dusts or mists.
Wash thoroughly after handling.
Use only outdoors or in a well-ventilated area.
Contaminated work clothing must not be allowed out of the workplace.
Wear protective gloves/protective clothing/eye protection/face protection.
If swallowed: Rinse mouth. Do NOT induce vomiting.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF INHALED: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Immediately call a poison center/doctor.
IF exposed or concerned: Get medical advice/attention.
Specific treatment (see on this label).
Get medical advice/attention if you feel unwell.
If skin irritation or rash occurs: Get medical advice/attention.
Wash contaminated clothing before reuse.
Store in a well-ventilated place. Keep container tightly closed.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
�� Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
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